A facile synthesis of 1, 4-dialkoxy-2, 5-diiodobenzenes: reaction of dialkoxybenzenes with iodine monochloride in alcoholic solvents

K Wariishi, S Morishima, Y Inagaki

Index: Wariishi, Koji; Morishima, Sin-Ichi; Inagaki, Yoshio Organic Process Research and Development, 2003 , vol. 7, # 1 p. 98 - 100

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Citation Number: 23

Abstract

A facile synthesis of 1, 4-dialkoxy-2, 5-diiodobenzenes via diiodination of the corresponding dialkoxybenzenes with iodine monochloride has been developed. Employment of an alcoholic solvent as a reaction medium is crucial for attaining a high yield; the reaction in a nonalcoholic solvent usually resulted in a poor yield. The diiodobenzene derivatives are useful intermediates in the synthesis of such advanced materials as soluble ...

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