Modification of Hydroxybenzopyranoids: Facile Deoxygenation of 2, 2-Dimethyl-7-hydroxy-4-chromanones and a New Approach to Their Novel Mercapto Analogs
P Sebok, T Timar, T Eszenyi…
Index: Sebok; Timar; Eszenyi; Patonay Journal of Organic Chemistry, 1994 , vol. 59, # 21 p. 6318 - 6321
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Citation Number: 25
Abstract
A facile deoxygenation of a systematic series of substituted 2, 2-dimethyl-7-hydroxy-4- chromanones via their sulfonate, isourea, and thiocarbamate derivatives is reported. The synthesis of novel 2, 2-dimethyl-7-mercapto-4-chromanones has been accomplished by the hydrolysis of the corresponding thiocarbamates. The scope and limitations of different deoxygenation procedures in the case of these hydroxybenzopyranoids are also ...
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