Reactions of N-(benzyloxycarbonyl) glycine and glycine tert-butyl ester with 2, 3-epoxypropyl pivalate

V Kellner, S Pokorný, M Kubín…

Index: Kellner,V. et al. Collection of Czechoslovak Chemical Communications, 1978 , vol. 43, p. 1694 - 1704

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Citation Number: 2

Abstract

N-(Benzyloxycarbonyl) glycine, glycine tert-butyl ester and 2, 3-epoxypropyl pivalate were prepared. The structure of pivalate was confirmed by the IR and IH-NMR spectra. GPC was used to investigate the reaction kinetics of N-(benzyloxycarbonyl) glycine with 2, 3- epoxypropyl pi val ate in N, N-dimethylformamide. The reaction is autocatalyzed by the hydroxy group of the forming product. Using the method of nonlinear regression, the rate ...