Tetrahedron

Original TDAE strategy using α-halocarbonyl derivatives

M Since, T Terme, P Vanelle

Index: Since, Marc; Terme, Thierry; Vanelle, Patrice Tetrahedron, 2009 , vol. 65, # 31 p. 6128 - 6134

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Citation Number: 24

Abstract

We report herein the selective C–C bond formation by the reaction of nitrobenzyl carbanions, formed via the TDAE strategy, with α-haloesters and α-haloamides. This reaction, extended in benzodioxole and dimethoxybenzene series provides new potentially CNS active agents.

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