Tetrahedron

Oxazoline Chemistry. Part 11: Syntheses of natural and synthetic isoflavones, stilbenes and related species via C–C bond formation promoted by a Pd–oxazoline …

CR Eisnor, RA Gossage, PN Yadav

Index: Eisnor, Charles R.; Gossage, Robert A.; Yadav, Paras N. Tetrahedron, 2006 , vol. 62, # 14 p. 3395 - 3401

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Citation Number: 44

Abstract

The complex trans-[PdCl2 (2-ethyl-2-oxazoline-κ1N) 2]() is shown to be an active and oxidatively robust catalyst for C–C bond forming reactions (Heck, Sonogashira, Ullmann, Miyaura–Suzuki, etc.). These reactions can be carried out in air without rigorous solvent/substrate purification and in the absence of additional free ligand. The general methodology described above has been applied to the high yield and regio-selective ...