The monofluorination of hydrofluorocarbons over cobalt trifluoride
S Kurosawa, A Sekiya, T Arimura, T Yamada
Index: Kurosawa, Shigeru; Sekiya, Akira; Arimura, Takashi; Yamada, Toshiro Journal of Fluorine Chemistry, 1993 , vol. 62, # 1 p. 69 - 76
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Citation Number: 13
Abstract
Abstract Hydrofluorocarbons (HFCs) have been fluorinated via the high-valency metal fluoridesCoF 3, MnF 3 and KCoF 4. The fluorinating powers of these reagents for the monofluorinationof 2, 2-difluoropropane are in the order CoF 3> MnF 3> KCoF 4. The fluorinations of fluorinatedethanes with CoF 3 have been examined in detail. The effects of temperature andthe distribution of products are described. Furthermore, regioselective ...
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