Highly selective hydrolytic kinetic resolution of terminal epoxides catalyzed by chiral (salen) CoIII complexes. Practical synthesis of enantioenriched terminal epoxides …

SE Schaus, BD Brandes, JF Larrow…

Index: Gurjar, Mukund K.; Sadalapure, Kashinath; Adhikari, Susanta; Sarma, Bugga V. N. B. S.; Talukdar, Arindam; Chorghade, Mukund S. Heterocycles, 1998 , vol. 48, # 7 p. 1471 - 1476

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Citation Number: 894

Abstract

... In nearly all cases, k rel values for the HKR exceed 50, and in several cases are well in ... 19 The cobalt analogues (R,R)-1 and (S,S)-1 proved equally accessible, and these are also ... In general, one volume of solvent relative to racemic epoxides was sufficient to allow efficient HKR ...

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