Isotopic exchange in the platinum-catalyzed reductions of olefins in protic solvents
TR Lee, GM Whitesides
Index: Randall Lee; Whitesides, George M. Journal of the American Chemical Society, 1991 , vol. 113, # 7 p. 2568 - 2576
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Citation Number: 10
Abstract
Abstract: This paper reports the isotopic compositions of alkanes obtained by the catalytic reductions of olefins using H2 or D2 and platinum black in alcoholic and mixed organic/aqueous solvents. The isotope found in the product alkanes was predominantly that present in the solvent (ROH or ROD) regardless of the isotope present in the gas (H2 or D2). The rate of exchange of isotopes of hydrogen between the protic solvent and the surface ...
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