Model studies of coenzyme B12 dependent diol dehydratase. 1. Synthetic, physical property, and product studies of two key, cobalt-bound, putative diol dehydratase …

…, WP McKenna, DA Schiraldi, BL Smith…

Index: Finke, Richard G.; McKenna, William P.; Schiraldi, David A.; Smith, Brad L.; Pierpont, Cortlandt Journal of the American Chemical Society, 1983 , vol. 105, # 26 p. 7592 - 7604

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Citation Number: 27

Abstract

Abstract: Following a brief introduction to the controversial question of cobalt participation or nonparticipation in the adenosylcobalamin (coenzyme BI2) dependent diol dehydratase rearrangement reaction, HOCH2CH20H-CH3CH0+ H20, the two key, cobalt-bound, putative diol dehydratase intermediates, CoCH (OH) CH20H (1) and CoCH2CH0 (2), are prepared and studied by using the coenzyme Biz, Schiff base, model system, RCo [C2 (D0)(DOH),] ...

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