Gas chromatography-mass spectrometry of osulose derivatives: O-trimethylsilyl, O-acetyl, O-isopropylidene, methyl glycosides, and 1, 1-dimethyl acetals

…, IC Travesedo, AS Martinez

Index: Ruiz, Pedro Antonio Garcia; Travesedo, Immaculada Cartagena; Martinez, Antonio Soler Canadian Journal of Chemistry, 1984 , vol. 62, p. 870 - 877

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Citation Number: 3

Abstract

Structure determination of the O-trimethylsilyl, O-acetyl, and O-isopropylidene derivatives of some hexosuloses, pentosuloses, and one tetrosulose, as well as their methyl glycosides and 1, 1-dimethyl acetals has been achieved by gas chromatography-mass spectrometry. By study based on the qualitative and quantitative differences in the 36 derivatives obtained, and their analogues prepared from tetradeuterio methanol and/or hexadeuterio acetone, ...