Aryl radicals from hexazadienes and tetrazenes
D Mackay, DD McIntyre
Index: Mackay, Donald; McIntyre, Deane Douglas Canadian Journal of Chemistry, 1982 , vol. 60, p. 990 - 999
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Abstract
Aryl radicals are produced from both ends of the hexazadienes 1 and 2 and from the tetrazene 3, either thermally or photolytically. They attack aromatic compounds in the nucleus, the yield of biaryl being in the range 40-70%, though it can be made nearly quantitative by using m-dinitrobenzene as an additive. The aryl radicals also oxidize 2- propanol to acetone, the reduction products being the halogenobenzene and 1, 2- ...
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