Catalytic Asymmetric Aziridination of α, β??Unsaturated Aldehydes
L Deiana, P Dziedzic, GL Zhao, J Vesely…
Index: Deiana, Luca; Dziedzic, Pawel; Zhao, Gui-Ling; Vesely, Jan; Ibrahem, Ismail; Rios, Ramon; Sun, Junliang; Cordova, Armando Chemistry - A European Journal, 2011 , vol. 17, # 28 p. 7904 - 7917
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Citation Number: 43
Abstract
Abstract The development, scope, and application of the highly enantioselective organocatalytic aziridination of α, β-unsaturated aldehydes is presented. The aminocatalytic azirdination of α, β-unsaturated aldehydes enables the asymmetric formation of β-formyl aziridines with up to> 19: 1 dr and 99% ee. The aminocatalytic aziridination of α- monosubstituted enals gives access to terminal α-substituted-α-formyl aziridines in high ...
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