Photoinduced electron transfer in a triad that can be assembled/disassembled by two different external inputs. Toward molecular-level electrical extension cables
R Ballardini, V Balzani, M Clemente-León…
Index: Ballardini, Roberto; Balzani, Vincenzo; Clemente-Leon, Miguel; Credi, Alberto; Teresa Gandolfi, Maria; Ishow, Elena; Perkins, Julie; Fraser Stoddart; Tseng, Hsian-Rong; Wenger, Sabine Journal of the American Chemical Society, 2002 , vol. 124, # 43 p. 12786 - 12795
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Citation Number: 130
Abstract
We have designed, synthesized, and investigated a self-assembling supramolecular system which mimics, at a molecular level, the function performed by a macroscopic electrical extension cable. The system is made up of three components, 1 2+, 2-H3+, and 3. Component 1 2+ consists of two moieties: a [Ru (bpy) 3] 2+ unit, which plays the role of an electron donor under light excitation, and a DB24C8 crown ether, which fulfills the function ...
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