Kinetics and mechanisms of nucleophilic displacement with heterocycles as leaving groups. 17. Solvolysis of 14-(primary alkyl)-5, 6, 8, 9-tetrahydro-7-phenyldibenzo [ …
…, Z Dega-Szafran, ML Lopez-Rodriguez…
Index: Katritzky, Alan R.; Dega-Szafran, Zofia; Lopez-Rodriguez, Maria L.; King, Roy W. Journal of the American Chemical Society, 1984 , vol. 106, # 19 p. 5577 - 5585
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Citation Number: 12
Abstract
Abstract: Solvolysis rates are reported for the Me, Et, n-Pr, n-Pent, n-Oct, i-Bu, neo-Pent, PhCH2CH2, and MeOCHzCHz title compounds in MeOH, EtOH, PentOH, CH3C02H, and CF, C02H. Rate variations with alkyl group structure are far less than the corresponding rate variations for the tosylate solvolyses, and afford no evidence for rate-enhancing participation by@ phenyl or@-methoxy groups in the acridinium solvolyses. The n-propyl, n-pentyl, and ...
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