The Journal of Organic Chemistry

Hydrogen Fluoride as a Condensing Agent. VI. Reactions of Fluoroölefins with Formaldehyde in Hydrogen Fluoride1

V Weinmayr

Index: Weinmayr,V. Journal of Organic Chemistry, 1963 , vol. 28, p. 492 - 494

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Citation Number: 36

Abstract

Tetrafluoroethylene condenses with formaldehyde in liquid hydrogen fluoride to form 2, 2, 3, 3, 3-pentafluoro-l-propanol and fluoromethyl-2, 2, 3, 3, 3-pentafluoropropyl ether. 2, 2, 3, 3- Tetrafluorooxetane, methyl-2, 2, 3, 3, 3-pentafluoropropyl ether, bis (2, 2, 3, 3, 3- pentafluoropropoxy) methane, and bis [(2, 2, 3, 3, 3-pentafluoropropoxy)-methyl] ether are formed as minor by-products. 2, 3, 3, 3-Tetrafluoro-2-trifluoromethyl-l-propanol is obtained ...