Tetrahedron

Reaction of organic sulfur compounds with superoxide anion—III: Oxidation of organic sulfur compounds to sulf1nic and sulfonic acids

S Oae, T Takata, YH Kim

Index: Oae, Shigeru; Takata, Toshikazu; Kim, Yong Hae Tetrahedron, 1981 , vol. 37, p. 37 - 44

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Citation Number: 47

Abstract

Organic sulfur compounds such as disulfide, thiolsulfinate, thiolsulfonate, thiol, sodium thiolate, and sodium sultinale were readily oxidized to both sulfinic and sulfonic acids with superoxide anion generated from potassium superoxide and 18-crown-6-ether under mild conditions. However, both sulfide and sulfoxide did not react with superoxide anion, O2-. Although thiol was easily oxidized to disulfide with O2− at room temperature, it was ...