Electrochimica acta

Electrochemistry of hypervalent compounds—V. Anodic oxidation of trivalent organoantimony and organobismuth compounds

T Fuchigami, M Miyazaki

Index: Fuchigami, Toshio; Miyazaki, Motoko Electrochimica Acta, 1997 , vol. 42, # 13-14 p. 1979 - 1984

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Citation Number: 6

Abstract

Anodic oxidation of triphenylantimony in the presence of various oxygen nucleophiles or halide ions provided the corresponding hypervalent compounds having Sb Y bonds (Y= RCOO, F, Cl, Br) in good yields. On the contrary, anodic oxidation of triphenylbismuth gave only carbon-bismuth bond cleavage products. Cathodic reduction of anodically synthesized hypervalent organoantimony compounds was also investigated by cyclic voltammetry.

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