The mechanism of the reaction of (aryloxy) trimethylstannane with methanesulfonyl chloride. Solvent and substituent effects on the rate of the reaction.

S Kozuka, S Yamaguchi, W Tagaki

Index: Kozuka; Yamaguchi; Tagaki Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 2 p. 573 - 576

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Citation Number: 4

Abstract

A kinetic study has been conducted on the reactions of (aryloxy) trimethylstannanes with methanesulfonyl chloride giving chlorotrimethylstannane and aryl methanesulfonates. The reaction was found to obey a second order kinetic equation. The solvent effect on the rate of the reaction appeared obscure although a small rate enhancement was observed in a polar solvent. Substituent effect of the aryloxyl group was found to be dependent on the solvent ...