Angewandte Chemie

Reduktion von Epoxiden, α, β??ungesättigten Aldehyden und vicinalen Diketonen mit „reaktivem Titanocen”

R Schobert

Index: Schobert, Rainer Angewandte Chemie, 1988 , vol. 100, # 6 p. 869 - 871

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Citation Number: 11

Abstract

Abstract Die Desoxygenierung von Epoxiden 2 zu Alkenen 3 gelingt mit „reaktivem Titanocen” stereoselektiv in hoher Ausbeute. Das Reagens wird aus 1 in situ erzeugt. Aus den beiden anderen Titelverbindungen sind Bis (allylalkohole) oder Bis (allyl) ether bzw.

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