Rearrangement of organometallic compounds. 25. Carbon-skeletal [1, 2] anionic rearrangements and the. pi.-orbital overlap constraint: the question of nucleophilic …
JJ Eisch, CA Kovacs, P Chobe
Index: Eisch, John J.; Kovacs, Csaba A.; Chobe, Prabohd Journal of Organic Chemistry, 1989 , vol. 54, # 6 p. 1275 - 1284
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Citation Number: 16
Abstract
Results Selection of Carbanion Substrates. In order to learn whether the n-overlap requirement would be a general constraint in skeletal rearrangement, we chose cyclic hydrocarbon, amine, and ether substrates, in which the starting carbanion would be constrained by the ring of which it was a member (encircled H in 11-16).
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