Reactions of metal-metal multiple bonds. 8. Forming molybdenum-molybdenum quadruple bonds by reductive elimination (alkyl group disproportionation) in the …

MJ Chetcuti, MH Chisholm, K Folting…

Index: Chetcuti, M. J.; Chisholm, M. H.; Folting, K.; Haitko, D. A.; Huffman, J. C. Journal of the American Chemical Society, 1982 , vol. 104, # 8 p. 2138 - 2146

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Citation Number: 33

Abstract

Abstract: Addition of C 0 2 and 1, 3-diaryltriazines to 1, 2-Mo2R2 (NMeJ4 compounds (M e M), where R= CH3 and CH2Si (CH3),, yields Mo2R2 (02CNMq), and Mo2R2 (NMq),(ArN3Ar), compounds, respectively, with retention of the M w M o bond, whereas related reactions, where R= C2H5, CH (CH3) 2, and n-, sec-, and t-C4Hg, yield Mo-Mo quadruply bonded compounds Mo2 (02CNMe2), and Mo2 (ArN3Ar), by reductive ...