Samarium (II) iodide-promoted intermolecular and intramolecular ketone-nitrile reductive coupling reactions
L Zhou, Y Zhang, D Shi
Index: Zhou, Longhu; Zhang, Yongmin; Shi, Daqing Synthesis, 2000 , # 1 p. 91 - 98
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Citation Number: 10
Abstract
Abstract: Samarium (II) iodide, a strong one-electron transfer reducing reagent, has been successfully utilized for the intermolecular and intramolecular reductive coupling reactions of ketones with nitriles. a-Hydroxy ketones, monocyclic, fused bicyclic a-hydroxy ketones and monocyclic a-amino alcohols composed of a number of substitution patterns have been prepared in good yields at room temperature or reflux under neutral conditions. The ...
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