A Halide-Free Method for Olefin Epoxidation with 30% Hydrogen Peroxide.

…, M Ogawa, T Hashimoto, D Panyella, R Noyori

Index: Sato, Kazuhiko; Aoki, Masao; Ogawa, Masami; Hashimoto, Tadashi; Panyella, David; Noyori, Ryoji Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 4 p. 905 - 915

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Citation Number: 182

Abstract

A catalytic system consisting of sodium tungstate dihydrate,(aminomethyl) phosphonic acid, and methyltrioctylammonium hydrogensulfate, effects the epoxidation of olefins using 30% hydrogen peroxide with a substrate-to-catalyst molar ratio of 50—500. The reaction ...