Structural, magnetic and optical properties of an Fe III dimer bridged by the meridional planar divergent N, N′-bis (salicyl) hydrazide and its photo-and electro- …

…, S Kouaho, G Rogez, S Dagorne, M Kurmoo…

Index: Cheaib, Khaled; Martel, David; Clement, Nicolas; Eckes, Fabrice; Kouaho, Stephanie; Rogez, Guillaume; Dagorne, Samuel; Kurmoo, Mohamedally; Choua, Sylvie; Welter, Richard Dalton Transactions, 2013 , vol. 42, # 5 p. 1406 - 1416

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Abstract

{FeIIICl (DMF) 2} 2 (L) where L is N, N′-bis (salicyl) hydrazide has been synthesized as red crystals and characterized using single-crystal diffraction, infrared and UV-vis spectroscopies, and its magnetic properties studied. The dimeric unit in the structure is formed through the two meridional sets of divergent O, N, O coordinating atoms of the hexacoordinated and quadruply charged ligand. With the presence of the inversion ...