Sulfinylamine metathesis at oxo metal species-convenient entry into imido metal chemistry
KA Rufanov, J Kipke, J Sundermeyer
Index: Rufanov, Konstantin A.; Kipke, Jennifer; Sundermeyer, Joerg Dalton Transactions, 2011 , vol. 40, # 9 p. 1990 - 1997
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Citation Number: 12
Abstract
The exchange of terminal metal oxo functionalities by N-organo and N-sulfonylimido functionalities viametathesis with bent, thus very reactive sulfinyl amines R-NSO and sulfinyl sulfonylamides R-SO2-NSO is described. It is demonstrated that in many cases sulfinyl amine metathesis offers a more convenient entry into imido complex synthesis than the much better investigated isocyanate metathesis at oxo complexes or condensation ...
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