Journal of the American Chemical Society

A Study of the Diels-Alder Addition Products of Hexachlorocyclopentadiene with: 1, 4-Dichlorobutene-2, 3, 4-Dichlorobutene-1 and 1, 4-Dichlorobutyne-2

PE Hoch, JM Clegg

Index: Hoch; Clegg Journal of the American Chemical Society, 1959 , vol. 81, p. 5413,5416

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Citation Number: 9

Abstract

Discussion In the early phase of the work, a mixture of cis-and trans-1, 4-dichlorobutene-2 was allowed to react with hexachlorocyclopentadiene. A solid product (I, 1n. p. 101-102') and a liquid product (11, bp 140-144'(0.1 mm.)) were obtained. Both of these products had the composition expected for the adduct. It was also demonstrated that the adduct of 3, 4- dichlorobutene-1 and hexachlorocyclopentadiene was identical to the liquid product 11.

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