Sulfonyl esters 3. The formation of sulfone-sulfonates in the reactions of aryl methanesulfonates with sodium hydride
…, KA Durkin, L Precedo, SB O'blenes…
Index: Baum, James Clayton; Durkin, Kathleen Anne; Precedo, Laura; O'Blenes, Stacy Brian; Goehl, John Edward; et al. Canadian Journal of Chemistry, 1991 , vol. 69, # 12 p. 2127 - 2135
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Abstract
Sodium hydride reductions of aryl methanesulfonates afford dimeric sulfone-sulfonate esters as well as products arising from SO bond rupture. SO bond rupture becomes more competitive as the LUMO energy of the sulfonate ester declines. Exploration of the chemistry of a sulfone-sulfonate ester revealed a complex novel reaction that resulted in the formation of, inter alia, a dichloromethanesulfonate ester and a trichloromethanesulfonate ester. The ...
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