Allylation of quinones with allyl (trifluoro) silanes: Direct synthesis of isoprenoid quinones
E Hagiwara, Y Hatanaka, K Gohda, T Hiyama
Index: Hagiwara, Emiko Tetrahedron Letters, 1995 , vol. 36, # 16 p. 2773 - 2776
Full Text: HTML
Citation Number: 16
Abstract
Allylation of a variety of quinones with allyl (trifluoro) silanes takes place with high regioselectivity in the presence of FeCl3· 6H2O, giving allylquinones in good yields. This method was used to synthesize biologically active isoprenoid quinones such as
Related Articles:
Allylation of quinones with allyltin reagents
[Naruta, Yoshinori Journal of the American Chemical Society, 1980 , vol. 102, # 11 p. 3774 - 3783]
[Bigi, Franca; Carloni, Silvia; Maggi, Raimondo; Muchetti, Chiara; Rastelli, Massimo; Sartori, Giovanni Synthesis, 1998 , # 3 p. 301 - 304]
Über ein neues Chinon aus höheren Pflanzen
[Bohlmann,F.; Kleine,K.-M. Chemische Berichte, 1966 , vol. 99, p. 885 - 888]
[Harwood; Oxford; Thomson Journal of the Chemical Society - Series Chemical Communications, 1991 , # 18 p. 1303 - 1305]
Allylation of quinones by allylic indium reagents
[Araki, Shuki; Katsumura, Nobuhito; Butsugan, Yasuo Journal of Organometallic Chemistry, 1991 , vol. 415, # 1 p. 7 - 24]