Palladium-catalyzed transfer hydrogenation in alkaline aqueous medium
…, M Pannala, AM Gonzalez, RM Chamberlin
Index: Arterburn; Pannala; Gonzalez; Chamberlin Tetrahedron Letters, 2000 , vol. 41, # 41 p. 7847 - 7849
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Citation Number: 28
Abstract
Catalytic transfer hydrogenation using palladium (II) chloride, formate and aqueous sodium hydroxide is effective for the reduction of unsaturated carboxylic acids, azalactones, and α- ketocarboxylic acids. This method is convenient, economical, avoids organic solvents, and uses a stable, nonpyrophoric catalyst.
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