Sequential One-Pot Reactions of Thioformamides with Organolithium and Zinc Reagents

T Murai, K Matsushita

Index: Murai, Toshiaki; Matsushita, Koji Phosphorus, Sulfur and Silicon and the Related Elements, 2011 , vol. 186, # 5 p. 1094 - 1103

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Abstract

Abstract Sequential one-pot reactions of thioformamides with organolithium and zinc reagents were carried out. As thioformamides, N, N-dimethylthioformamide and N- ethoxycarbonyl N′-thioformyl piperazine were used. A variety of organolithium reagents such as alkyl, aryl, and heteroaryllithiums were used to give the corresponding amines in moderate to high yields. The efficiency of the reaction was influenced by the substituents ...

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