Distinguishing Between Pathways for Transmetalation in Suzuki− Miyaura Reactions

BP Carrow, JF Hartwig

Index: Huser, Marc; Youinou, Marie-Therese; Osborn, John A. Angewandte Chemie, 1989 , vol. 101, # 10 p. 1427 - 1430

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Citation Number: 198

Abstract

... Volume: Page: ... presence of PPh 3 (0.15 M) was monitored (Figure 1) at −40 °C and occurred with an observed rate constant of 2.4 × 10 −3 s −1 .(15) In contrast, no reaction was observed between halide complex 3 and potassium p-tolyltrihydroxyborate (0.15 ...