Self-condensation of n-butyraldehyde over solid base catalysts
H Tsuji, F Yagi, H Hattori, H Kita
Index: Tsuji, Hideto; Yagi, Fuyuki; Hattori, Hideshi; Kita, Hideaki Journal of Catalysis, 1994 , vol. 148, # 2 p. 759 - 770
Full Text: HTML
Citation Number: 191
Abstract
Abstract The catalytic properties of various solid bases for self-condensation of n- butyraldehyde in liquid phase were studied to elucidate the factors governing the activity and selectivity. For alkaline earth oxide catalysts and γ-alumina catalyst, aldol condensation occurred, followed by Tishchenko-type cross-esterification of n-butyraldehyde with the dimer produced by the aldol condensation to form trimeric glycol ester. Alkali ion-modified ...
Related Articles:
Trimerization of aliphatic aldehydes to 1, 3-diol monoesters catalyzed by Cp∗ 2 Sm (thf) 2
[Miyano, Akira; Tashiro, Daisuke; Kawasaki, Yumi; Sakaguchi, Satoshi; Ishii, Yasutaka Tetrahedron Letters, 1998 , vol. 39, # 38 p. 6901 - 6902]