The Journal of Organic Chemistry

. beta.'Metalation of. alpha.,. beta.-unsaturated tertiary amides

DJ Kempf, KD Wilson, P Beak

Index: Kempf, Dale J.; Wilson, Kenneth D.; Beak, Peter Journal of Organic Chemistry, 1982 , vol. 47, # 8 p. 1610 - 1612

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Citation Number: 20

Abstract

Summary: Novel p'metalations of the a, p-unsaturated tertiary amides N, N-diisopropyl-1- cyclohexenecarbox-amide (3),(E)-NJV-diisopropyl-2-methyl-2-butenamide (7), and N, N- diisopropyl-6-(trimethylsilyl)-l-cyclohexene-carboxamide (10) are reported. Additions of the p'-lithio-a, p-unsaturated tertiary amides 4, 8, and 11 to a