Catalytic synthesis of methylene diphenyl dicarbamate from methyl phenyl carbamate and trioxane over sulfuric acid catalyst
T Li, H Li, G Qin, H Liu, Y Pei
Index: Li, Tao; Li, Huiquan; Qin, Guotong; Liu, Haitao; Pei, Yixia Frontiers of Chemistry in China, 2010 , vol. 5, # 1 p. 99 - 103
Full Text: HTML
Citation Number: 1
Abstract
Abstract Methylene diphenyl dicarbamate (MDC) was synthesized from methyl phenyl carbamate (MPC) and trioxane using sulfuric acid (H 2 SO 4) as catalyst. The effects of reaction temperature, reaction time, molar ratio of reactants and the content of catalyst have been studied in details. The results showed that H 2 SO 4 exhibited high catalytic activity with the merits of moderate reaction velocity. Under the conditions of n (MPC)/n (trioxane) ...
Related Articles:
Effect of Soft Segment Polydispersity on the Elasticity of Polyurethane Elastomers
[Caraculacu, Adrian A.; Agherghinei, Ion; Gaspar, Mariana; Prisacariu, Cristina Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1990 , # 8 p. 1343 - 1348]
[Jakus, Vladimir; Bojsova, Eva Collection of Czechoslovak Chemical Communications, 1992 , vol. 57, # 7 p. 1505 - 1515]