Synthesis, structural and spectroscopic characterization of thiophosphorodiamidates and effect of ZnCl 2 on the hydrolysis of the P–N bond

P Malik, D Chakraborty

Index: Malik, Payal; Chakraborty, Debashis Polyhedron, 2013 , vol. 52, p. 831 - 836

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Abstract

New N, N′-dibenzylthiophosphorodiamidate derivatives were synthesized from the corresponding thiophosphorodichloridate intermediates and benzylamine. Several compounds with formula 2-MeC6H4OP (S)(NHBn) 2 (6), 2-FC6H4OP (S)(NHBn) 2 (7), 2- ClC6H4OP (S)(NHBn) 2 (8), 4-MeC6H4OP (S)(NHBn) 2 (9) and 4-t-BuC6H4OP (S)(NHBn) 2 (10) were synthesized and characterized by 1H, 13C, 31P NMR, IR, mass spectroscopy ...