Decomposition of sulfonyl azides and tert-butyl azidoformate by transition metal carbonyls

RA Abramovitch, GN Knaus…

Index: Abramovitch,R.A. et al. Journal of Organic Chemistry, 1974 , vol. 39, p. 2513 - 2516

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Citation Number: 6

Abstract

Iron and cobalt Complexes [Fe (RS02N) &O. H20], and [CO (RSO~ N)~ CO.~/~ H~ O], which are deficient of terminal and bridging metal carbonyls have been isolate,.; om the reaction of methane-, benzene-, and p-toluenesulfonyl azide with iron pentacarbonyl, diiron nonacarbonyl, and dicobalt octacarbonyl. Hydrolysis of these with dilute hydrochloric acid leads to the corresponding N, N'-bis (sulfony1) urea. Possible structures for the complexes ...