Chemistry of Allene. IV. Carbonylation Reactions of Allene
TJ Kealy, RE Benson
Index: Kealy,T.J.; Benson,R.E. Journal of Organic Chemistry, 1961 , vol. 26, p. 3126 - 3130
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Citation Number: 46
Abstract
The carbonylation of allene in water in the presence of ruthenium catalysts has given methacrylic acid. Derivatives ctf methacrylic acid were obtained when the reaction was conducted in the presence of methanol or amines. I-nder certain conditions a lactone, 3- hydrosy-1, 3, 4-trimethylcyclohexanecarboxylic acid lactone, or an ester, dimethyl or, a- diniethyl-u'-niethyl-eneglutarate, were the major products of the carbonylation reaction in ...
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