Formation of 1, 3-di (2-fluorenyl)-1-butene from 2-(1-bromoethyl) fluorene with silver powder.

M Minabe, M Suzuki, T Ooya, K Suzuki

Index: Minabe,M. et al. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 544 - 546

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Abstract

An unexpected compound, 1, 3-di (2-fluorenyl)-1-butene, was formed as the major product, accompanied by meso-and dl-2, 3-di (2-fluorenyl) butane as the minor products, in the reaction of 2-(1-bromoethyl) fluorene with silver powder. The structure of the butene was confirmed to be the E form by a comparison of the UV spectra of the related compounds.

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