Metal complexes-catalyzed hydrolysis and alcoholysis of organic substrates and their application to kinetic resolution
M Tokunaga, H Aoyama, J Kiyosu, Y Shirogane…
Index: Tokunaga, Makoto; Aoyama, Hiroshi; Kiyosu, Junya; Shirogane, Yuki; Iwasawa, Tetsuo; Obora, Yasushi; Tsuji, Yasushi Journal of Organometallic Chemistry, 2007 , vol. 692, # 1-3 p. 472 - 480
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Citation Number: 2
Abstract
Metal complexes-catalyzed hydrolysis and alcoholysis of organic substrates such as alkenyl esters, alkenyl ethers, and azlactones (oxazol-5 (4H)-ones) are described. These reactions were applied for kinetic resolution of chiral compounds and high selectivities were achieved with vinyl ethers of 2-substituted cyclohexanols, 1, 1′-bi-2-naphthols, 1, 1′-bi-2-phenols, and 4, 4-disubstituted azlactones. Oxidative carbon–carbon bond cleavage reactions, ...
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