The reactions of ethyl-, vinyl-, and ethynyl (trichloromethyl) carbinols with aqueous and methanolic potassium hydroxide, thiourea, and cyanamide
W Reeve, TF Steckel
Index: Reeve, Wilkins; Steckel, Thomas F. Canadian Journal of Chemistry, 1980 , vol. 58, p. 2784 - 2788
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Citation Number: 9
Abstract
The reactions of ethyl (trichloromethyl) carbinol, dimethyl (trichloromethyl) carbinol,( trichloromethyl) vinylcarbinol, ethynyl (trichloromethyl) carbinol, and 1, 1, 1,-triehloro-3- nonyn-2-ol have been studied with the following reagents. Methanolic potassium hydroxide: α-methoxy acids are formed in 70 and 79% yields with the ethyl-and vinylcarbinols respectively. Double bond migration to the conjugated position was observed with the ...
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