Synthesis of 1, 2-cycloalkanediols by intramolecular titanium-induced pinacol coupling
JE McMurry, JG Rico
Index: McMurry, John E.; Rico, Joseph G. Tetrahedron Letters, 1989 , vol. 30, # 10 p. 1169 - 1172
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Citation Number: 77
Abstract
Abstract Seven representative 1, 2-cycloalkanediols of ring size 6-14 were prepared in high yield by titanium-induced pinacol coupling of dialdehydes. Cis stereochemistry predominated in six-and eight-membered rings, but trans products were formed in ring sized ten and above.
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