Tocopherols by hydride reduction of dialkylamino derivatives

T Netscher, F Mazzini, R Jestin

Index: Netscher, Thomas; Mazzini, Francesco; Jestin, Roselyne European Journal of Organic Chemistry, 2007 , # 7 p. 1176 - 1183

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Citation Number: 16

Abstract

Abstract Aminomethylation with Mannich reagents derived from secondary amines and paraformaldehyde under improved conditions has been used to convert non-α-tocopherol homologues into α-tocopherol, the biologically most important vitamin E compound. Mono- and bis (aminomethylated) β-, γ-and δ-tocopherol were then subsequently transformed into the corresponding tocopherols (α-and β-tocopherol) by reductive deamination. As an ...

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