Palladium-imidazolinium carbene-catalyzed arylation of aldehydes with arylboronic acids in water
M Kuriyama, N Ishiyama, R Shimazawa, O Onomura
Index: Kuriyama, Masami; Ishiyama, Natsuki; Shimazawa, Rumiko; Onomura, Osamu Tetrahedron, 2010 , vol. 66, # 34 p. 6814 - 6819
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Citation Number: 14
Abstract
The catalytic arylation of aldehydes with arylboronic acids in only water was found to be achieved using the palladium/thioether-imidazolinium chloride system in good to excellent yields. This catalytic process showed high tolerance for a broad range of substrates, giving a variety of carbinol derivatives with 2.0–3.0 mol% of the catalyst.
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