Journal of the American Chemical Society

Benzoxazolone Formation in the Attempt to Prepare Certain Mixed Diacyl Derivatives of o-Aminophenol

LC Raiford, GO Inman

Index: Raiford; Inman Journal of the American Chemical Society, 1934 , vol. 56, p. 1586,1587

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Citation Number: 17

Abstract

When two different acyl radicals are introduced into o-aminophenol the positions taken by these groups are determined by a number of fa. ct0rs. l If the acyls are R-~ O and R!-C= C),~ the heaviest and most acidic radical is usually found attached to nitrogen, regardless of the order of introd~ ction.~ To meet this requiremerit the migration of acyl from nitrogen to oxygen must occur in one of these reactions. When the acyls are R-&= CJ and R--QC= O ...