Tetrahedron letters

Bromonitrile oxide [3+ 2] cycloadditions in water

JC Rohloff, J Robinson, JO Gardner

Index: Rohloff, John C.; Robinson, James III; Gardner, John O. Tetrahedron Letters, 1992 , vol. 33, # 22 p. 3113 - 3116

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Citation Number: 40

Abstract

Abstract Bromonitrile oxide can be generated homogeneously in water at acidic pH, allowing efficient [3+ 2] cycloaddition with water soluble olefins and acetylenes. Allylammonium salts react with high regioselectivity and without the need for N-group protection.

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