Endohedral metallocenophanes of rhodium and cobalt

C Schaefer, G Scholz, R Gleiter…

Index: Schaefer, Carsten; Scholz, Gerald; Gleiter, Rolf; Oeser, Thomas; Rominger, Frank European Journal of Inorganic Chemistry, 2005 , # 7 p. 1274 - 1281

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Citation Number: 6

Abstract

Abstract The synthesis of seven endohedral metallocenophanes of rhodium (7b, 8b) and cobalt (1d− h) with a cyclopentadienyl unit as one of the π-systems and a cyclobutadiene or cyclopentadienone unit as the second π-system is described, including the synthesis of the unsubstituted parent compound of the [CpCo (cbd)]-derived endohedral phanes,[3.3]-η 5-(1, 1', 3, 3')-cyclopentadienyl–η 4-(cyclobutadienophane) co-balt (I)(1h). This compound ...