Organometallics

Coordination chemistry of Group 14 metalloles. 5. Use of dicarbonyl (. eta. 5-cyclopentadienyl)(1-methyl-2, 5-diphenylsilacyclopentadien-1-yl) iron as a four-electron …

E Colomer, RJP Corriu, M Lheureux

Index: Colomer, Ernest; Corriu, Robert J. P.; Lheureux, Marc Organometallics, 1989 , vol. 8, p. 2343 - 2348

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Abstract

Chlorine is displaced in l-chloro-l-methyl-2, 5-diphenylsilole by dicarbonyl (q5- cyclopentadienyl) ferrate (I) to give a silole with a Si-Fe u bond. Attempts to displace the carbonyl ligands to give the corresponding silaferrocene were unsuccessful. This new dole behaves as an efficient q4-ligand with transition metals, giving a new series of complexes which present an interesting reactivity. Thus the Si-Fe bond can be cleaved without ...

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