Cationic organometallic complexes with hexaalkylborazines: I. Synthesis and reactivity of cationic hexamethylborazinerhodium complexes with carbonyl, ethylene and …

M Scotti, M Valderrama, R Ganz, H Werner

Index: Scotti, M.; Valderrama, M.; Ganz, R.; Werner, H. Journal of Organometallic Chemistry, 1985 , vol. 286, p. 399 - 406

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Citation Number: 10

Abstract

Abstract The PF 6 salts of the new cationic hexamethylborazinerhodium (I) complexes of general formula [Rh (Me 3 B 3 N 3 Me 3)(LL′)]+(LL′= 1, 5-cyclooctadiene, norbornadiene, tetrafluorobenzobarrelene, trimethyltetrafluorobenzobarrelene, L= L′= ethylene, CO) have been prepared from the reaction between [RhCl (LL′)] 2, Me 3 B 3 NMe 3, and AgPF 6 in dichloromethane. These complexes are very labile, undergoing rapid ring ligand ...