The Addition of Silicon Hydrides to Olefinic Double Bonds. XI. Exchange of Methyl and Trimethylsiloxy Groups in Bistrimethylsiloxymethylsilane

MR Stober, MC Musolf, JL Speier

Index: Stober,M.R. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 1651 - 1652

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Citation Number: 27

Abstract

2 (MesSiO) zSiMeH+ MeaSiOSiMezH+(MesSiO) aSiH and tristrimethylsiloxysilane. No example has been observed previously of such a reaction under the mild conditions of these experiments. A study of the addition of bis (trimethylsi1oxy) methylsilane [I,(Me3SiO) 2SiMeH], to hexene-2 in the presence of chloroplatinic acid revealed a most unexpected side reaction. An exchange of methyl and trimethyldoxy groups occurred in a way never ...