Synthesis of SF 5 benzene (SF 5 C 6 H 5) by the SF 5 halide method

RW Winter, GL Gard

Index: Winter, Rolf W.; Gard, Gary L. Journal of Fluorine Chemistry, 2004 , vol. 125, # 4 p. 549 - 552

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Citation Number: 28

Abstract

Through progress in understanding the reactivity of SF 5 halides (SF 5 X), both primary synthons, SF 5 Br and SF 5 Cl were utilized in order to synthesize the benzotrifluoride analog, pentafluorothiobenzene (SF 5 C 6 H 5 ) from cyclohexene or derivatives of cyclohexene. These new processes readily produce pentafluorothiobenzene in high yields. One may consider SF 5 C 6 H 5 a primary synthon in its own right and it has found application ...